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Posts Tagged ‘Tesla

battery technology and the cobalt problem

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The battery in my iPhone 6+ is described as a lithium polymer, or Li-ion polymer battery. I’m trying to find out if it contains cobalt. Why? Because cobalt is a problem.

According to this Techcrunch article, most of the world’s cobalt is currently sourced from Africa, especially the Congo, one of the world’s poorest countries. Child labour is regularly used in the mines there, under pain of beatings and other forms of coercion. The battery industry uses about 42% of global cobalt production, and the rest is used in a range of essential military-industrial applications.

Incidentally, this article from teardown.com blog goes deep inside the iPhone 6+ battery, showing that it uses lithium cobalt oxide (LiCoO2) for the cathode.

I can think of three possible ways out of this problem. 1. Stop sourcing cobalt from the Congo, or anywhere else that has exploitative labour practices. 2. Reform those labour practices, to improve the lives of the workers and provide them with a fairer share of the tech revolution profits. 3. Find an alternative to cobalt for batteries and other applications.

I didn’t say there were easy solutions haha. Anyway, let’s examine them.

An online Fortune article from March this year, which by the way confirms that cobalt is indeed used in iPhone and iPad batteries, reported that Apple has responded to investigative articles by Washington Post and Sky News by no longer buying cobalt from companies that employ child labour. Of course, even if we take Apple at its word – and considering that the Congo provides 60% of the world’s cobalt, and other African sources may have similar problems, how else will Apple be able to source cobalt cheaply? – the problem of Congolese child labour remains. The Washington Post report focused on a Chinese company, Zhejiang Huayou Cobalt Company, which purchases a large percentage of Congolese cobalt. It seems highly unlikely that such a company will be as affected by public or media pressure as Apple. However, there are some positive signs. A report in the Financial Times from a year ago, entitled ‘China moves to quell child labour claims in Congo cobalt mines’, says that China has launched a ‘Responsible Cobalt Initiative’ to improve supply chain governance and transparency. Whether this means applying solution 1 or solution 2 to the problem is unclear, but presumably it’s solution 2, and it really is a serious initiative, put forward by the Chinese Chamber of Commerce for Metals, Minerals and Chemicals Importers and Exporters, backed by the OECD and involving a number of international tech companies. Of course we’ll have to wait for reports on how this initiative is faring, and on whether these companies are concerned to improve the lives of cobalt miners or simply to ban the under-age ones while still paying very little to the remainder. Continued scrutiny is obviously necessary.

Of course, solution 3 would be of most interest to tech-heads (though presumably the effect on the Congolese economy would be terrible). According to this marketing article, there isn’t too much cobalt available, and the demand for it is increasing sharply. One problem is that cobalt isn’t generally mined on its own as ‘primary cobalt’ but as a byproduct of copper or nickel, and both of these metals are experiencing a worldwide price plunge, with many mines suspending activities. Also the current supply chain for cobalt is being dominated by Chinese companies. This could have a stifling effect especially on the EV revolution. Governments in advanced countries around the world – though not in Australia – are mandating the adoption of electric vehicles and the phasing out of fossil-fuel-based road transport. The batteries for these vehicles all contain cobalt.

In the TechCrunch article mentioned above, journalist Sebastien Gandon examines the Tesla situation. The company has a target of 500,000 vehicles a year by 2018, with cobalt sourced exclusively from North America. On the face of it, this seems unrealistic. Canada and the US together produce about 4% of the world’s cobalt supply, and  acccording to Gandon the maths just doesn’t add up, to say the least. For a start, the mining companies Tesla is looking to rely on are not even operational as yet.

However, there are a few more promising signs. The Tesla model S has been using high energy density nickel-cobalt-aluminium-based (NCA) battery cells, which have a lower cobalt content than the nickel-manganese-cobalt (NMC) batteries of most other companies. There is also the possibility of adopting lithium-iron-phosphate (LFP) chemistry, or lithium-manganese-oxide (LMO), neither of which use cobalt, though their lower energy density is a problem. In any case, battery technology is going through a highly intensive phase at present, as I’ve already reported, and a move away from cobalt has become a distinct possibility. Nickel is currently being looked at, but results so far have been disappointing. There are certainly other options in the offing, and cobalt itself, which unlike oil is completely recyclable, could still be viable with greater focus. It isn’t so much that it is scarce, it’s more that, in the past, it hasn’t been a primary focus, but mining it as a primary source will require substantial upfront costs, and substantial time delays.

So, all in all, it’s a problematic future, at least in the short term, for vehicles and technologies using cobalt-based battery systems. We can only wait and see what comes out of it.

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Written by stewart henderson

October 28, 2017 at 12:55 pm

on the explosion of battery research – part two, a bitsy presentation

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This EV battery managed to run for 1200 kilometres on a single charge at an average of around 51 mph

Ok, in order to make myself fractionally knowledgable about this sort of stuff I find myself watching videos made by motor-mouthed super-geeks who regularly do blokes-and-sheds experiments with wires and circuits and volt-makers and resistors and things that go spark in the night, and I feel I’m taking a peek at an alternative universe that I’m not sure whether to wish I was born into, but I’ll try anyway to report on it all without sounding too swamped or stupefied by the detail.

However, before I go on, I must say that, since my interest in this stuff stems ultimately from my interest in developing cleaner as well as more efficient energy, and replacing fossil fuel as a principal energy source, I want to voice my suspicions about the Australian federal government’s attitude towards clean and renewable energy. This morning I heard Scott Morrison, our nation’s Treasurer, repeating the same deliberately misleading comments made recently by Josh Frydenberg (the nation’s energy minister, for Christ’s sake) about the Tesla battery, which is designed to provide back-up power as part of a six-point SA government plan which the feds are well aware of but are unwilling to say anything positive about – or anything at all. Morrison, Frydenberg and that other trail-blazing intellectual, Barnaby Joyce, our Deputy Prime Minister, have all been totally derisory of the planned battery, and their pointlessly negative comments have thrown the spotlight on something I’ve not sufficiently noticed before. This government, since the election of just over a year ago, has not had anything positive to say about clean energy. In fact it has never said anything at all on the subject, by deliberate policy I suspect. We know that our PM isn’t as stupid on clean energy as his ministers, but he’s obviously constrained by his conservative colleagues. It’s as if, like those mythical ostriches, they’re hoping the whole world of renewables will go away if they pay no attention to it.

Anyway, rather than be demoralised by these unfortunates, let’s explore the world of solutions.

As a tribute to those can-do, DIY geeky types I need to share a great video which proves you can run an electric vehicle on a single charge for well over 1000ks – theirs made it to 1200ks – 748 miles in that dear old US currency – averaging around 51 mph. It’s well worth a watch, though with all the interest there are no doubt other claimants to the record distance for a single charge. Anyway, you can’t help but admire these guys. Tesla, as the video shows, are still trying to make it to 1000ks, but that’s on a regular, commercial basis of course.

In this video, basically an interview with battery researcher and materials scientist Professor Peter Bruce at Oxford University, the subject was batteries as storage systems. These are the batteries you find in your smart phones and other devices, and in electric vehicles (EVs). They’ll also be important in the renewable energy future, for grid storage. You can pump electricity into these batteries and, through a chemical process that I’m still trying to get my head around, you can store it for later use. As Prof Bruce points out, the lithium-ion battery revolutionised the field by more or less doubling the energy density of batteries and making much recent portable electronics technology possible. This energy density feature is key – the Li-ion batteries can store more energy per unit mass and volume. Of course energy density isn’t the only variable they’re working on. Speed of charge, length of time (and/or amount of activity) between charging, number of discharge-recharge cycles per battery, safety and cost are all vitally important, but when we look at EVs and grid storage you’re looking at much larger scale batteries that can’t be simply upgraded or replaced every few months. So Bruce sees this as an advantage, in that recycling and re-using will be more of a feature of the new electrified age. Also, as very much a  scientist, Bruce is interested in how the rather sudden focus on battery storage reveals gaps in our knowledge which we didn’t really know we had – and this is how knowledge often progresses, when we find we have an urgent problem to solve and we need to look at the basics, the underlying mechanisms. For example, the key to Li-ion batteries is the lithium compound used, and whether you can get more lithium ions out of particular compounds, and/or get them to move more quickly between the electrodes to discharge and recharge the battery. This requires analysis and understanding at the fundamental, atomistic level. Also, current Li-ion batteries for portable devices generally use cobalt in the compound, which is too expensive for large-scale batteries. Iron, manganese and silicates are being looked at as cheaper alternatives. This is all new research – and he makes no mention of the work done by Goodenough, Braga et al.

In any case it’s fascinating how new problems lead to new solutions. The two most touted and developed forms of renewable energy – solar and wind – both have this major problem of intermittence. In the meantime, battery storage, for portable devices and EVs, has become a big thing, and now new developments are heating up the materials science field in an electrifying way, which will in turn hot up the EV and clean energy markets.

The video ended by neatly connecting with the geeky DIY video in showing how dumped, abandoned laptop batteries and other batteries had plenty of capacity left in them – more than 60% in many cases, which is more than useful for energy storage, so they were being harvested by PhD students for use in small-scale energy storage systems for developing countries. Great for LED lighting, which requires little power. The students were using an algorithm to get each battery in the system to discharge at different rates (since they all had different capacities or charge left in them) so they could get maximum capacity out of the system as a whole. I think I actually understood that!

Okay – something very exciting! The video mentioned above is the first I’ve seen of a British series called ‘Fully Charged’, all about batteries, EVs and renewable energy. I plan to watch the series for my education and for the thrill of it all. But imagine my surprise when I started watching this one, still part of the series, made here in Adelaide! I won’t go into the content of that video, which was about flow batteries which can store solar energy rather than transferring it to the grid. I need to bone up more on that technology before commenting, and it’s probably a bit pricey for the likes of me anyway. What was immediately interesting to me was how quickly he (Robert Llewellyn, the narrator/interviewer) cottoned on to our federal government’s extreme negativity regarding renewables. Glad to have that back-up! I note too, by the way, that Australia has no direct incentives to buy EVs, of which there are few in the country – again all due to our troglodyte government. It’s frankly embarrassing.

So, there’s so much happening with battery technology and its applications that I might need to take some time off to absorb all the videos and docos and blogs and podcasts and development plans and government directives and projects and whatnot that are coming out all the time from the usual and some quite unusual places, not to mention our own local South Australian activities and the naysayers buzzing around them. Then again I may be moved to charge forward and report on some half-digested new development or announcement tomorrow, who knows….

References

They’re all in the links above, and I highly recommend the British ‘Fully Charged’ videos produced by Robert Llewellyn and Johnny Smith, and the USA ‘jehugarcia’ videos, which, like the Brit ones but in a different way, are a lot of fun as well as educational.

 

Written by stewart henderson

August 1, 2017 at 9:26 pm

How will the super-duper Tesla battery work? And more on the price of electricity

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Image: Thermo Fisher Scientific Inc.

I received an email the other day from the Australia Insitute. I don’t know how that happened, I’ve never heard of the organisation. Apparently it’s Australia’s most influential progressive think-tank (self-described) and apparently I subscribed to it recently while in a barely conscious state. All good.

Anyway the topic was timely: ‘Rising Energy Bills: Blame Gas’.

In a very recent post I quoted from a few apparently reliable sources on the reason for South Australia’s very high electricity prices. Unfortunately there wasn’t too much agreement among them, though at least none of them blamed renewable energy. But neither did any of them blame gas, though one did point a finger at wholesale pricing. The Australia Institute’s email put it thus:

Yesterday, we released the latest Electricity Update of the National Energy Emissions Audit for July 2017. The report revealed a stunning correlation between domestic electricity prices and gas prices — particularly in South Australia — despite gas making up only 10 percent of electricity generation.

So this is a subject I need to return to – in my next post. This post will focus on batteries and storage.

Neoen, a French renewable energy company, is building a 315MW, 99 turbine wind farm near Jamestown in South Australia. Connected to this project will be an array of Tesla’s lithium ion Powerpack batteries. According to this ABC News article:

The array will be capable of an output of 100 megawatts (MW) of power at a time and the huge battery will be able to store 129 megawatt hours (MWh) of energy so, if used at full capacity, it would be able to provide its maximum output for more than an hour.

It will be a modular network, with each Powerpack about the size of a large fridge at 2.1 metres tall, 1.3m long and 0.8m wide. They weigh in at 1,200 kilograms each.

It will have just slightly more storage than the next biggest lithium battery, built by AES this year in southern California.

But Tesla’s 100 MW output would be more than three times larger than the AES battery and five times larger than anything Tesla has built previously.

I’m no electrochemist, but a nice scrutiny of these sentences identifies a clear distinction between output and storage. And the output of this planned battery is the pioneering aspect.

So here’s a very basic summary of how a rechargeable lithium ion battery works. Each battery (and they vary hugely in size) is made up of a number of cells, each a battery in itself. On opposite sides of the cell are conductive surfaces, aka current collectors, one of aluminium and the other of copper. Inside and joined to these surfaces are electrodes, the positive cathode and the negative anode. The cathode is made from a lithium metal oxide such as lithium cobalt oxide or lithium iron phosphate, which needs to have the purest, most uniform composition for maximum performance and longevity. The negative anode is made from graphite, a layered form of carbon. The layered structure allows the lithium ions (Li+) created by the current to be easily stored at and removed from the carbon surface. Between these electrodes, filling the cell, is an electrolyte fluid through which lithium ions flow from one electrode to the other, which charges and discharges the cell. Again the purity of this fluid is a vital factor (research is being done to come up with a form of solid electrolyte). Between the two electrodes is an insulating plastic separator, essential to keep the electrodes separate and prevent short-circuiting. This plastic membrane allows the lithium ions to pass through it. The battery is charged when the lithium ions have passed through the separator and become attached to and stored in the layered graphite of the anode. The battery is discharged by reversing the flow.

Lithium ion batteries are found not only in Tesla Powerpacks but generally in electric car batteries and many other devices such as my own iPhone and iPad. They’re lighter and have much less energy density than lead-acid batteries. The technology of lithium ion batteries is described in a number of useful online videos, of which the most comprehensive, I think, is a webinar from the American Chemistry Society (ACS), essentially an interview with Dee Strand, a lithium ion battery specialist and expert. Her talk also provides interesting ideas on how these types of batteries can be improved.

So a fully-charged cell has stored energy, and a discharging cell is producing output. There are variations in lithium ion battery technology, for example variations in the electrode materials, the electrolyte composition and the like, so we don’t know precisely what Tesla will be using for the South Australian battery system, but we have a fair idea.

In any case, there seems no obvious reason why this proven technology can’t be scaled up to meet the sort of need that was identified after last September’s state blackout. Now we just have to wait and see whether Musk will lose his bet regarding completion time come December.

Refs and info

http://www.tai.org.au/

http://www.abc.net.au/news/2017-07-07/what-is-tesla-big-sa-battery-and-how-will-it-work/8688992

https://www.thermofisher.com/content/dam/tfs/ATG/CMD/cmd-documents/sci-res/pub/comm/env/AR-Lithium-Ion-Battery-Degradation-RandD-Mag-042214.pdf

http://www.abc.net.au/news/2017-07-07/sa-to-get-worlds-biggest-lithium-ion-battery/8687268

Just type in ‘lithium ion battery’ in youtube

 

 

Written by stewart henderson

July 19, 2017 at 1:00 pm

What’s Weatherill’s plan for South Australia, and why do we have the highest power prices in the world? Oh, and I should mention Elon Musk here – might get me more hits

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just a superhero pic to rope people in

I’ve written a few pieces on our electricity system here in SA, but I don’t really feel any wiser about it. Still, I’ll keep having a go.

We’ve become briefly famous because billionaire geek hero Elon Musk has promised to build a ginormous battery here. After we had our major blackout last September (for which we were again briefly famous), Musk tweeted or otherwise communicated that his Tesla company might be able to solve SA’s power problems. This brought on a few local geek-gasms, but we quickly forgot (or I did), not realising that our good government was working quietly behind the scenes to get Musk to commit to something real. In March this year, Musk was asked to submit a tender for the 100MW capacity battery, which is expected to be operational by the summer. He has recently won the tender, and has committed to constructing the battery in 100 days, at a cost of $50 million. If he’s unsuccessful within the time limit, we’ll get it for free.

There are many many South Australians who are very skeptical of this project, and the federal government is saying that the comparatively small capacity of the battery system will have minimal impact on the state’s ‘self-imposed’ problems. And yet – I’d be the first to say that I’m quite illiterate about this stuff, but if SA Premier Jay Weatherill’s claim is true that ‘battery storage is the future of our national energy market’, and if Musk’s company can build this facility quickly, then it’s surely possible that many batteries could be built like the one envisaged by Musk, each one bigger and cheaper than the last. Or have I just entered cloud cuckoo land? Isn’t that how technology tends to work?

In any case, the battery storage facility is designed to bring greater stability to the state’s power network, not to replace the system, so the comparisons made by Federal Energy Minister Josh Frydenberg are misleading, probably deliberately so. Frydenberg well knows, for example, that SA’s government has been working on other solutions too, effectively seeking to becoming independent of the eastern states in respect of its power system. In March, at the same time as he presented plans for Australia’s largest battery, Weatherill announced that a taxpayer-funded 250MW gas-fired power plant would be built. More recently, AGL, the State’s largest power producer and retailer, has announced  plans to build a 210MW gas-fired generator on Torrens Island, upgrading its already-existing system. AGL’s plan is to use reciprocating engines, which executive general manager Doug Jackson has identified as best suited to the SA market because of their ‘flexible efficient and cost-effective synchronous generation capability’. I heartily agree. It’s noteworthy that the AGL plan was co-presented by its managing director Andy Vesey and the SA Premier. They were at pains to point out that the government plans and the AGL plan were not in competition. So it does seem that the state government has made significant strides in ensuring our energy security, in spite of much carping from the Feds as well as local critics – check out some of the very nasty naysaying in the comments section of local journalist Nick Harmsen’s articles on the subject (much of it about the use of lithium ion batteries, which I might blog about later).

It’s also interesting that Harmsen himself, in an article written four months ago, cast serious doubt on the Tesla project going ahead, because, as far as he knew, tenders were already closed on the battery storage or ‘dispatchable renewables’ plan, and there were already a number of viable options on the table. So either the Tesla offer, when it came (and maybe it got in under the deadline unbeknown to Harmsen), was way more impressive than others, or the Tesla-Musk brand has bedazzled Weatherill and his cronies. It’s probably a combo of the two. Whatever, this news is something of a blow to local rivals. What is fascinating, though is how much energetic rivalry, or competition, there actually is in the storage and dispatchables field, in spite of the general negativity of the Federal government. It seems our centrist PM Malcolm Turnbull is at odds with his own government about this.

So enough about the Tesla-Neoen deal, and associated issues, which are mounting too fast for me to keep up with right now. I want to focus on pricing for the rest of this piece, because I have no understanding of why SA is now paying the world’s highest domestic electricity prices, as the media keeps telling us.

According to this Sydney Morning Herald article from nearly two years ago, which of course I can’t vouch for, Australia’s electricity bills are made up of three components: wholesale and retail prices, based on supply and demand (39% of cost); the cost of poles and wires (53%); and the cost of environmental policies (8%). The trio can be simplified as market, network and environmental costs. Market and network costs vary from state to state. The biggest cost, the poles and wires, is borne by all Australian consumers (at least all on the grid), as a result of a massive $45 billion upgrade between 2009 and 2014, due to expectations of a continuing rise in demand. Instead there’s been a fall, partly due to domestic solar but in large measure because of much tighter and more environmental building standards nationwide as part of the building boom. The SMH article concludes, a little unexpectedly, that the continuing rise in prices can only be due to retail price hikes, at least in the eastern states, because supply is steady and network costs, though high, are also steady.

A more recent article (December 2016) argues that a rising wholesale price, due to the closure of coal-fired power stations in SA and Victoria and higher gas prices, is largely responsible. Retail prices are higher now than when the carbon tax was in place in 2013.

This even recenter article from late March announces an inquiry by the Australian Competition and Consumer Commission (ACCC) into retail pricing of electricity, which unfortunately won’t be completed till June 30 2018, given its comprehensive nature. It also contains this telling titbit:

A report from the Grattan Institute released earlier in March found a decade of competition in the market had failed to deliver better deals for customers, with profit margins on electricity bills much higher than for many other industries.

However, another article published in March, and focusing on SA’s power prices in particular (it’s written by former SA essential services commissioner Richard Blandy), takes an opposing view:

Retailing costs are unlikely to be a source of rapidly rising electricity prices because they represent a small proportion of final prices to consumers and there is a high level of competition in this part of the electricity supply chain. Energy Watch shows that there are seven electricity retailers selling electricity to small businesses, and 12 electricity retailers selling electricity to households. Therefore, price rises at the retail level are likely to be cost-based.

Blandy’s article, which looks at transmission and distribution pricing, load shedding and the very complex issue of wholesale pricing and the National Energy Market (NEM), needs at least another blog post to do justice to. I’m thinking that I’ll have to read and write a lot more to make sense of it all.

Finally, the most recentest article of only a couple of weeks ago quotes Bruce Mountain, director of Carbon and Energy Markets, as saying that it’s not about renewables (SA isn’t much above the other states re pricing), it’s about weak government control over retailers (could there be collusion?). Meanwhile, politicians obfuscate, argue and try to score points about a costly energy system that’s failing Australian consumers.

I’ll be concentrating a lot on this multifaceted topic – energy sources, storage, batteries, pricing, markets, investment and the like, in the near future. It exercises me and I want to educate myself further about it. Next, I’ll make an effort to find out more about, and analyse, the South Australian government’s six-point plan for our energy future.

References and more reading for masochists

http://www.abc.net.au/news/2017-03-10/tesla-boss-elon-musk-pledges-to-fix-sas-electricity-woes/8344084

http://www.adelaidenow.com.au/business/sa-government-announces-who-will-build-100mw-giant-battery-as-part-of-its-energy-security-plan/news-story/9f83072547f41f4f5556477942168dd9

http://www.smh.com.au/business/sunday-explainer-why-is-electricity-so-expensive-20150925-gjvdrj.html

http://www.skynews.com.au/business/business/market/2017/03/27/accc-to-find-out-why-power-prices-are-so-high.html

http://www.adelaidenow.com.au/news/south-australia/south-australia-will-have-highest-power-prices-in-the-world-after-july-1-increases/news-story/876f9f6cefce23c62395085c6fe0fd9f

http://indaily.com.au/news/business/analysis/2017/03/07/why-sas-power-prices-are-so-high-and-the-huge-risks-of-potential-fixes/

http://www.theaustralian.com.au/opinion/columnists/graham-richardson/jay-weatherill-must-come-clean-on-elon-musks-battery-deal/news-story/f471b33ebdf140a71b41e0b0bea7894f

http://www.news.com.au/technology/environment/climate-change/why-higher-electricity-prices-are-inevitable/news-story/042712e35c08bf798ed993d13ee573ea

Written by stewart henderson

July 14, 2017 at 10:55 am